This research aims to implement a strategy of using a controlled acidic etching on AlSi alloy particles to partially remove Al and preserve a porous Si framework as anode materials. The etched AlSi materials with different Al/Si weight ratios have been investigated in lithium-ion batteries. Microstructural analysis shows the evolution of the AlSi material during selective wet etching, highlighting the preservation of coral-shaped Si nanostructures with an Al-rich core. Lower Al/Si ratios result in increased surface area and pore volume, which is favorable for improving lithium-ion diffusion and accommodating volume expansion during cycling. Evaluation of electrochemical performance in different electrolytes proves the importance of electrolyte selection for AlSi anodes. The tetrahydrofuran-based (THF-based) electrolyte stabilizes electrochemical reactions, resulting in superior specific capacity, cycle life, and Coulombic efficiency compared to the carbonate-based electrolyte with fluoroethylene carbonate additive. Rate performance analysis shows excellent high-rate capability with stable capacity retention at 3C, particularly in Al53Si47 and Al10Si90 materials. Electrochemical impedance spectroscopy measurements emphasize the critical role of porous structure and electrolytes in sustaining low resistance and enhancing cycle life performance. Selective aluminum etching and the THF-based electrolyte effectively mitigate the breakdown and subsequent reformation of the solid electrolyte interphase, resulting in superior efficiency and extended lifespan.
This letter proposes a compact, low-profile, and battery-free wireless sensor, capable of continuously monitoring spoilage gases, such as ammonia (NH3), in meat and seafood products. The wireless sensor consists of a high-Q microstrip antenna loaded with a varactor diode, whose capacitance is reconfigured by an electrochemical ammonia (NH3) sensor such that the resonance frequency of antenna can be tuned by ammonia levels. This (receiving) antenna sensor operating at the fundamental frequency f0 is connected to a passive frequency doubler and a wideband monopole (transmitting) antenna operating at the second harmonic 2f0, within a compact tag. By receiving and re-transmitting radio waves with orthogonal frequencies under the frequency hopping spread spectrum (FHSS) framework, electromagnetic interferences caused by clutters and jamming can be filtered out, thus ensuring robust wireless food sensing with absolute accuracy in noisy environments. The effectiveness and robustness of the proposed sensor are demonstrated through remote monitoring of the spoilage process of packaged fish within two days. Results show that the ammonia concentration can be sensed by tracking the peak frequency of the received strength signal indicator (RSSI) at harmonic frequencies. This passive RFID sensor, with minimal footprint, complexity, and low cost, may be readily placed into the food package/container, enabling real-time assessment and forecasting of food quality and safety.
With finals approaching, the BEST Lab took a much-needed break for a team lunch. We gathered at a cozy local restaurant (Woosa), enjoying delicious food/pancakes and great company. Laughter filled the air as we shared lab stories, research highlights, and study tips (I'm kidding!). This outing reminded us of the importance of taking breaks and supporting each other, especially during stressful times. Recharged and connected, we returned to our workstations, ready to tackle the final stretch of the semester. Here’s to a successful exam season and more shared moments!
